赵冰，博士，教授，毕业于天津大学。

人才称号：黑龙江省应用化学领军人才梯队后备带头人

齐齐哈尔市应用化学领军人才梯队带头人

通讯地址：齐齐哈尔市文化大街42号化学与化学工程学院轻纺楼623

电话：0452-2738309

电子邮件：837426092@qq.com

课题组网站：

研究领域：功能性共价有机框架的构建及应用研究

小分子荧光探针的设计及应用工程

招生学科：化学工程与技术(应用化学)，化学(物理化学)，材料与化工类

教育及科研经历：

1995-1999年辽宁科技大学化工学院精细化工专业本科

2002-2005年天津大学理学院有机化学硕士

2005-2008年天津大学化工学院应用化学博士

2008年至今齐齐哈尔大学化学与化学工程学院学院硕士生导师

2015-2016年美国弗吉尼亚大学化学系访问学者

2015年至今齐齐哈尔大学化学与化学工程学院学院教授

荣誉和奖励

奖励

1.杂环硫乙酰氨类杯[4]芳烃衍生物的合成及离子识别性能的研究，黑龙江省科学技术奖(自然科学类)三等奖，黑龙江省人民政府，2016-08-30。

2.基于稠环及多芳基咪唑长波长荧光探针的设计及接力识别性能研究，黑龙江省高校科学技术奖二等奖，黑龙江省高校科学技术委员会，2020-12-21。

荣誉

齐齐哈尔市第十届优秀科技工作者

学术兼职：

中国化工学会精细化工专委会委员

黑龙江省化工学会第五届理事会常务理事

黑龙江省工业和信息化厅专家库专家

黑龙江省国资委投资咨询专家库专家

科研论文

1.Chunyu Bi,Bing Zhao*, Wang Zheng, Mo Sun, Wei Kan *, Liyan Wang, Li Sun, Xiuwen Wang, Ming Zhao*, Highly efficient adsorption and capture of prevalent phenolic contaminants from the real samples by trifluoromethyl-functionalized covalent organic frameworks,Separation and Purification Technology, 2024, 339, 126631 (DOI: 10.1016/j.seppur.2024.126631).

2.Pengfei Zhang, Jin Qi, Ran Zhang, Yifan Zhao, Jingyu Yan, Yajuan Gong, Xiaoming Liu, Binbin Zhang, Xiao Wu, Xiuping Wu, Cheng Zhang,BingZhao*, Li Bing, Recent advances in composite hydrogels: synthesis, classification, and application in the treatment of bone defects,Biomaterials Science, 2023, 12, 2, 308-329 (DOI: 10.1039/d3bm01795h)

3.Qiushuang Li,Bing Zhao*, Xiangdong Kong a, Liyan Wang, Wei Kan, Bo Song, Rui Yu a, Pengfei Zhang，Multi-responsive fluorescent covalent organic framework based on phenanthro[9,10-d]imidazole moiety for relayed detection of Cu2+/Al3+ followed by PO₄^3–and its applications，Dyes and Pigments, 2024, 222, 111886(DOI:10.1016/j.dyepig.2023.111886)

4.Lin Yue, Jiayu Zhang, Zhihao Zeng, Chunran Zhao, Xin Hu, Leihong Zhao,Bing Zhao*,and Yiming He*, In situ fabrication of an S‐scheme nanbo3/Bi₂O₂CO₃heterojunction for enhanced performance in photocatalytic nitrogen fixation,Langmuir, 2023, 39, 13267?13278(DOI: 10.1021/acs.langmuir.3c01725)

5.Rui Yu, Wei Kan,*, Xin Qi, Yue Zhang, Limin Ding,*, Liyan Wang,Bing Zhao,*An ICT phenanthro[9,10-d]imidazole-based fluorescence probe with aggregated characteristic for colorimetric detection of hypochlorous acid and its applications in water samples andliving cells,Inorganica Chimica Acta, 2023, 558,121724(DOI:10.1016/j.ica.2023.121724)

6.Shaoxin Li,Bing Zhao*, Wei Kan*, Tianshu Song, Wang Zheng, Xin Qi, Liyan Wang, Bo Song, A fluorescent covalent organic framework with a brick-wall topology for the detection of Cu2+ promoted by the associated mechanism,Dyes and Pigments, 2023, (214), 111178, (DOI: 10.1016/j.dyepig.2023.111178)

7.Huagen Liang, Zejia Gai, Fu Chen, Shengyu Jing*, Wei Kan,Bing Zhao*, Shibin Yin, Panagiotis Tsiakarasf, Fe3C decorated wood-derived integral N-doped C cathode for rechargeable Li-O2 batteries,Applied Catalysis B: Environmental, 2023, 324, 122203 (DO: 10.1016/j.apcatb.2022.122203)

8.Zhigang Li,Bing Zhao*, Wei Kan*, Fanqiang Bu, Xin Qi, Liyan Wang, Bo Song, Limin Ding. An acid-triggered reactive and enhanced fluorescent probe for selective detection of Al3+/H+ and its application in real water samples and living cells,Journal of Fluorescence, 2023, 33, 91–101 (DOI:10.1007/s10895-022-03039-5)

9.Wang Zheng?, Anran Li?, Xiuwen Wang*, Zhigang Li,Bing Zhao*,Liyan Wang, Wei Kan*, Li Sun, Xin Qi. Construction of hydrophilic covalent organic frameworks and their fast and efficient adsorption towards cationic dyes from aqueous solution,New Journal of Chemistry, 2022, 46, 22185–22194 (DOI: 10.1039/d2nj04336j)

10.Lantian Li,? Anran Li,?Bing Zhao*, Wei Kan*, Chunyu Bi, Wang Zheng, Xiuwen Wang, Li Sun, Liyan Wang and Hongrui Zhang. Multi-sulfonated functionalized hydrophilic covalent organic framework for highly efficient dye removal from real samples, New Journal of Chemistry, 2022, 46, 17016–17025 (DOI: 10.1039/d2nj02857c)

11.李安然,赵冰*,阚伟*,宋天舒,孔祥东,卜凡强,孙立,殷广明,王丽艳.基于菲并咪唑ON?OFF?ON双比色荧光探针及细胞成像.高等学校化学学报, 2021, 42(8), 2403–2411 (DOI: 10.7503/cjcu20210089)

12.Jiahui Du,Bing Zhao*, Wei Kan*, Haochun Yin, Tianshu Song, Liyan Wang, Li Sun, Xiuwen Wang, Guangming Yin and Jianxin Wang. A phenanthrene[9,10-d]imidazole-phenol-based fluorescent probe combined ESIPT and AIE for “turn-on” detection of Cu²⁺with a green-emitting and improved stokes shift and its application.New Journal of Chemistry, 2021, 45(34), 15415–15422 (DOI: 10.1039/D1NJ02177J)

13.Fanqiang Bu,Bing Zhao*, Wei Kan*, Limin Ding*, Ting Liu, Liyan Wang, Bo Song, Wenbo Wang, Qigang Deng. An ESIPT characteristic “turn-on” fluorescence sensor for Hg²⁺with large Stokes shift and sequential “turn-off” detection of S^2–as well as the application in living cells.Journal of Photochemistry & Photobiology A: Chemistry, 2020, 387, 112165, (DOI: doi.org/10.1016/j.jphotochem.2019.112165).

14.Haochun Yin,Bing Zhao*, Wei Kan*, Limin Ding*, Liyan Wang, Bo Song, Wenbo Wang, Qigang Deng. A phenanthro[9,10-d]imidazole-based optical sensor for dual-responsive turn-on detection of acidic pH and Cu²⁺in chicken blood and living cells.Dyes and Pigments, 2020, (173), 107916, (DOI:0.1016/j.dyepig.2019.107916).

15.Yuqian He,Bing Zhao*, Wei Kan*, Limin Ding*, Zhaochuan Yu, Mingyue Wang, Bo Song and Liyan Wang. Two isomeric and distinguishable H2S fluorescence probes for monitoring spoilage of eggs and visualizing exogenous and endogenous H₂S in living cells.Analyst, 2020, 145, 213–222 (DOI: 10.1039/c9an01629e).

16.何玉倩，赵冰*，阚伟*，王丽艳，宋波，殷广明，毕野，陈书文.基于ESIPT和AIE活性的菲并咪唑Fe³⁺荧光探针及细胞成像研究.有机化学，2019, 39(11), 3250–3257(DOI: 10.6023/cjoc201904078).

17.Bing Zhao *, Yuqian He, Wei Kan *, Fengqiao Kong, Liyan Wang, Bo Song, Wenbo Wang, Guangming Yin, Jianxin Wang. SelectiveN-alkylation of 2-amino-4H-chromene-3-carbonitrile derivatives with alcohols catalyzed by AlCl₃under the assistance of CH₃COOH,Chemical Research in Chinese Universities, 2019, 35 (6), 997–1001 (DOI: 10.1007/s40242-019-9248-5).

18.Bu Fanqiang,Zhao Bing*, Kan Wei*, Wang Liyan, Song Bo, Wang Jianxin, Zhang Zhe, Deng Qigang, Yin Guangming. A phenanthro[9,10-d]imidazole-based AIE active fluorescence probe for sequential detection of Ag⁺/AgNPs and SCN^–in water and saliva samples and its application in living cells,Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2019, 217, 18–26 (DOI: 10.1016/j.saa.2019.117333).

19.白雨弘旭，赵冰*，何玉倩，杨宜璇，葛薇，陈明明，张立鑫.增强型四苯基咪唑类荧光探针及其对硫醇的识别性能.精细石油化工, 2019,36(4), 79–84.

20.Haochun Yin,Bing Zhao*, Wei Kan*, Ting Liu, Wenbo Wang, Guangming Yin, Wang Liyan, Gao Yan*, Wang Jianxin. Hydroxyl phenyl imino modified phenanthro[9,10-d] imidazole: An AIEE-active sensor for determination of Cu²⁺in water samples and subsequent "turn-on" recognition of Cr³⁺with logic gates,Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2019, 217, 18–26 (DOI: 10.1016/j.saa.2019.03.060).

21.Wei Wang, Jian Wu, Qinglei Liu, Gao Yan, Huimin Liu,Bing Zhao. A highly selective coumarin-based chemosensor for the sequential detection of Fe³⁺and pyrophosphate and its application in living cell imaging.Tetrahedron Letters, 2018, 59(19), 1860–1865.

22.赵冰*，何玉倩，阚伟*，李少鑫，王丽艳，阚宏泽，刘双义.基于荧光素-罗丹明B的比色探针对Cu2+和EDTA的接力识别.精细石油化工, 2018，35(5), 60–65.

23.李少鑫，阚伟*，赵冰*，李慧婷，王丽艳，刘双义，阚宏泽.基于荧光素-罗丹明B的双Schiff碱选择性紫外识别Fe³⁺的探针.精细石油化工, 2018, 35(2), 58–63.

24.Shaoxin Li, Wei Kan*,Bing Zhao*, Liu Ting, Fang Yue, Bai Liming and Wang Liyan, A fluorescent pH probe for an aqueous solution composed of 7-hydroxycoumarin, Schiff base and phenanthro[9,10-d]imidazole moieties (PICO).Heterocyclic Communications, 2018, 24(2), 93–97 (DOI: 10.1515/hc-2017-0174).

25.Shaoxin Li, Bing Zhao*, Wei Kan, Liyan Wang, Bo Song, and Shuwen Chen*. A off–on pH fluorescence probe derived from phenanthro[9,10-d] imidazol-fluorescein based on ESIPT and ICT,Research on Chemical Intermediates, 2018, 44(1), 491–502. (DOI: 10.1007/s11164-017-3115-0) (IDS No: FS2LC).

26.Bing Zhao *, Ting Liu, Yue Fang, Liyan Wang, Wei Kan, Qigang Deng *, and Bo Song. A new selective chemosensor based on phenanthro[9,10-d] imidazole-coumarin with sequential “on-off-on” fluorescence response to Fe³⁺and phosphate anions and its application in live cell,Sensors & Actuators: B. Chemical, 2017, 246, 370–379. (DOI: 10.1016/j.snb.2017.02.079).

27.李少鑫，阚伟*，赵冰*，白丽明，刘婷，王丽艳，宋波.氨基乙酰肼链接的荧光素-菲并咪唑衍生物的合成与表征.精细石油化工, 2017, 34(5), 26–31.

28.孔凤巧，赵冰*，姜黎黎，王丽艳，邓启刚.微波辐射下合成1,3-二取代苯基-3-(苯并噻唑-2-氨基)-1-丙酮衍生物.精细石油化工, 34(3), 2017, 1–7.（2017-05-18）

29.刘婷，赵冰*，李少鑫，房跃，王丽艳，宋波.乙酰氨基链接的菲并[9,10-d]咪唑-香豆素衍生物的合成.化学研究与应用, 2017, 29(7), 999–1005.

30.赵冰*，刘婷，王丽艳，邓启刚. Schiff碱链接的双菲并咪唑Fe3+荧光探针的合成及识别性能研究.化学试剂,2017,39(1),1–5;10.

31.赵冰*，李少鑫，马明杰，邓启刚，王丽艳，阚伟，冯亚青.含乙氧甲酰甲氨基咪唑杯[4]芳烃的合成及其水相体系中对Al3+和Ag+的荧光识别.精细化工,2016,33(10),1189–1194(DOI:10.13550/j.jxhg.2016.10.019 ).

32.Bing Zhao*, Ting Liu, Yue Fang, Liyan Wang, Song Bo and Deng Qigang*. Two “turn-off” Schiff-base fluorescence sensors based on phenanthro [9,10-d]imidazole-coumarin derivatives for Fe³⁺in aqueous solution,Tetrahedron Letters, 2016, 57(39), 4417–4423 (DOI: 10.1016/j.tetlet.2016.08.064).

33.Bing Zhao*, Yue Fang, Yu Xu, Qigang Deng, Ting Liu, Wei Kan, and Liyan Wang. Dual-responsive pH sensor based on a phenanthro[9,10-d]imidazole fluorophore modified by amino diacetate.Tetrahedron Letters, 2016, 57(16), 1825–1830 (DOI: 10.1016/j.tetlet.2016.03.046).

34.Bing Zhao*, Yu Xu, Qigang Deng, Wei Kan, Yue Fang, Liyan Wang, Yan Gao. Modified 1H-phenanthro[9,10-d]imidazole derivative with the double acetohydrazide as fluorescent probe for sequential detection of Ni²⁺and Al³⁺with ‘on–off–on’ response.Tetrahedron Letters, 2016, 57(8), 953–958 (DOI: 10.1016/j.tetlet.2016.01.065)

35.赵冰*，姜黎黎，邓启刚，王丽艳，宋波.一锅三组分合成2取代-1,4-2H-咪唑并[4,5-b]吲哚衍生物.化学世界,2016,57(1),43–47.

36.Wei Kan, Tao Jing, Xiaohong Zhang, Yongjie Zheng, Lin Chen,Zhao Bing*. Microwave-assisted one pot synthesis ofN-substituted 2-methyl -1H-pyrrole-3-carboxylate derivatives without catalyst and solvent,Heterocycles, 2015, 91(12), 2367–2376 (DOI: 10.3987/COM-15-13340).

37.Bing Zhao, Lili Jiang, Zhuo Liu, Qigang Deng, Liyan Wang, Bo Song, Yan Gao. Microwave-assisted Michael addition of 2-amino pyridine to chalcones under catalyst-free conditions,Research on Chemical Intermediates, 2015, 41, 5809–5819 (DOI: 10.1007/s11164-014-1703-9).

38.Bing Zhao, Yu Xu, Mingjie Ma, Qigang Deng. A selective fluorescence probe for copper(II) ion in aqueous solution based on 4-(1,4,5-triphenyl-1H-imidazol-2- yl)anilinyl acetates,Research on Chemical Intermediates, 2015, 41, 8031–8040 (DOI: 10.1007/s11164-014-1875-3).

39.Bing Zhao, Yue Fang, Mingjie Ma, Qigang Deng, Yu Xu, Liyan Wang. A new on-fluorescent sensor for Ag⁺based on benzimidazole bearing bis(ethoxycarbonyl methyl)amino groups.Heterocyclic Communications, 2015, 21(4), 211–214 (DOI: 10.1515/hc-2015-0002).

40.Bing Zhao, Yu Xu, Yue Fang, Liyan Wang Qigang, Deng. Synthesis and fluorescence properties of phenanthro[9,10-d] imidazole derivative for Ag⁺in aqueous media.Tetrahedron Letters, 56(19), 2015, 2460–2465. (DOI: 10.1016/j.tetlet.2015.03.094).

41.赵冰,马明杰,阮耀宇,王丽艳,阚伟,宋波,石克炘.含氨基乙酸酯苯并咪唑杯[4]芳烃荧光分子探针的合成及光谱性能.化学试剂, 2015,37（6）,545–548；560.

42.Bing Zhao, Yu Xu, Qigang Deng, Zhuo Liu, Liyan Wang, Yan Gao. One-pot, three component synthesis of novel 5H-[1,3,4]thiadiazolo[3,2-a]pyrimidine- 6-carboxylate derivatives by microwave irradiation.Tetrahedron Letters, 2014, 55(33), 4521–4524 (DOI: 10.1016/j.tetlet.2014.06.073).

43.Bing Zhao, Lili Jiang, Zhuo Liu, Qigang Deng*, Liyan Wang, Song Bo, and Gao Yan, A microwave assisted synthesis of highly substituted 7-methyl- 5H-thiazole[3,2-a]pyridmidine -6-carboxylate derivatives via one pot reaction of aminothiazole, aldehyde and ethyl acetoacetate.Heterocycles, 87(10), 2013, 2093–2102 (DOI: 10.3987/COM-13-12797)

44.Bing Zhao, Yaoyu Ruan, Mingjie Ma, Qigang Deng*, Liyan Wang, Yaqing Feng, and Yan Gao. One-pot synthesis of 11,23-bis(imidazol-1-yl)calix[4]arene derivatives based on the upper rim of bis-aminocalix[4]arene.Heterocycles, 2013, 87(9), 1917–1924 (DOI: 10.3987/COM-13-12771).

45.Bing Zhao, Yacui Zhou, Mengjiao Fan, Zhiyu Li, Liyan Wang, Qigang Deng. Synthesis, fluorescence properties and selective Cr(III) recognition of tetraaryl imidazole derivatives bearing thiazole group.Chinese Chemical Letters, 2013, 24, 257–259 (DOI: 10.1016/j.cclet.2013.01.031).

46.Bing Zhao, Yaoyu Ruan, Qigang Deng, Liyan Wang, Bo Song and Yaqing Feng. Synthesis and characterization of heteroarylthio derivatives of 5, 17-di-tert-butyl-11, 23-diamido-25, 27-diprotected calix[4]arene.Heterocyclic Communication, 2013, 1, 19–22 (DOI: 10.1515/hc-2012-0154).

47.Bing Zhao, Mengjiao Fan, Zhuo Liu, Lifeng Hu, Bo Song, Liyan Wang and Qigang Deng.Reformatsky reaction promoted by an ionic liquid ([Bmim]Cl) in the synthesis ofβ-hydroxyl ketone derivatives bearing a coumarin unit,Journal of Chemical Research, 2012, 6, 393–395 (DOI: 10.3184/174751912X13371 652436057).

科研项目

1.硫酸钾制粒项目实施关键技术攻关与转化，项目负责人，黑龙江省省属高等学校基本科研业务费科研项目，2023—2025。

2.新型“双响应”荧光共价有机框架的构建及响应机制研究，项目负责人，国家自然科学基金面上项目，2021—2024。

3.荧光型共价有机框架材料的设计及生物学响应特征研究，项目负责人，黑龙江省重点研发计划指导项目，2021—2023。

4.基于AIEE和ESIPT的菲并咪唑白光探针的设计和性能研究，项目负责人，黑龙江省级领军人才梯队后备带头人资助项目，2018—2021。

5.基于多重响应机理协同作用的双光子荧光探针的合成及识别性能研究，项目负责人，黑龙江省省属高等学校基本科研业务费科研项目，2018—2020。

6.基于荧光探针法检测酒类饮品中Cu2+含量的研究，项目负责人，黑龙江省省属高等学校基本科研业务费科研项目（植物性食品加工技术特色学科专项），2018—2020。

7.基于稠(多)芳基咪唑tweezers结构荧光分子的构建及其识别性能研究，项目负责人，黑龙江省科学基金留学归国人员科学基金项目，2017—2020。

8.基于稠环及多芳基咪唑长波长荧光分子探针的设计及接力识别性能研究，项目负责人，国家自然基金青年科学基金项目，2016—2018。

9.基于杯芳烃的多芳基咪唑双功能荧光分子探针的设计合成及性能研究，项目负责人，黑龙江教育厅面上项目，2014—2015。

10.杂环硫乙酰氨类杯[4]芳烃衍生物的合成及离子识别性能的研究，项目负责人，黑龙江省科技厅青年基金项目，2010—2012。

专利

1.赵冰，李秋爽，李元琪，李兰天，阚伟，王丽艳，王秀文，孙立，杜研，沈思宇，沈晓亮。一种杂原子掺杂共价有机框架材料及其制备方法与应用，发明专利，专利号ZL 2022 1 0842324.4，授权日期2024.02。

2.赵冰，卜凡强，宋天舒，阚伟，王文波，殷广明，王丽艳。一种裸眼或荧光检测Ag⁺双菲并咪唑探针及使用方法，发明专利，专利号ZL201811192860.4，授权日期2021.01。

3.赵冰，卜凡强。一种裸眼或荧光Al3+探针及其制备方法和应用，发明专利，ZL 201911000088.6，授权日期2023.09。

4.赵冰，李秋爽，李元琪，孔祥东，阚伟，王丽艳，王秀文，孙立，杜研，沈思宇，沈晓亮。一种Cu2+和Al3+双功能荧光共价有机框架材料及其制备方法和应用，发明专利，ZL 2022 1 0740307.X，授权日期2023.07。

5.赵冰，郑旺，李志刚，赵立杰，阚伟，王丽艳，孙立，王秀文。一种用于对苯二酚吸附的共价有机框架材料及其制备方法和应用，发明专利，ZL202111515003.5，授权日期2023.06。

6.赵冰，李志刚，阚伟，李安然，郑旺，卜凡强，王丽艳，宋波，孙立，王秀文。一种实时检测亚硫酸氢根离子的荧光探针及其制备方法与应用，发明专利，ZL 202111542466.0，授权日期2023.03。

7.赵冰，李安然，孔祥东，杜佳慧，阚伟，卜凡强，王丽艳，孙立，王秀文。一种光谱法和比色法检测不同形式碘的分子平台及其制备方法和应用，发明专利，ZL202010794666.4，授权日期2022.08。

8.赵冰，宋天舒，李安然，孔祥东，阚伟，王丽艳，孙立，王秀文。一种Cu2+荧光共价有机框架材料及其制备和应用，发明专利，ZL 202110170647.9，授权日期2022.06。

9.赵冰，卜凡强，宋天舒，阚伟，王文波，殷广明，王丽艳。一种裸眼或荧光检测Ag+双菲并咪唑探针及使用方法，发明专利，ZL2018 1 1192860.4，授权日期2021.01。

10.赵冰，刘婷，孔凤巧，李少鑫，阚伟，王丽艳。可逆双羟基菲并咪唑Hg2+荧光探针及其合成与使用方法，发明专利，ZL201611019074.5，授权日期2020.08。

11.赵冰，孔凤巧，卜凡强，李少鑫，刘婷，王丽艳，阚伟，宋波。一种Lewis/Bronsted酸促进下醇参与的2-氨基色烯衍生物N-烷基化方法，发明专利，专利号ZL201710255046.1，授权日期2019.06。

12.赵冰，卜凡强，何玉倩，李少鑫，尹浩纯，阚伟，王丽艳。一种用于裸眼检测的荧光素-罗丹明B铜离子紫外分子探针及其合成和使用方法，发明专利，专利号ZL201711088730.1，授权日期2019.05。

13.赵冰，宋波，李少鑫，孔凤巧，刘婷，阚伟，王丽艳。三羟基咪唑-荧光素pH荧光探针及其制备方法，发明专利，专利号ZL201611047563.1，授权日期2019.05。

14.赵冰，刘婷，邓启刚，王丽艳，阚伟，宋波。双Schiff碱链接的对称型菲并咪唑Fe³⁺荧光探针及制备方法，发明专利，专利号ZL201610201233.7，授权日期2017.09。

15.赵冰。一种用于铁离子检测的菲并咪唑-香豆素双荧光基团比率荧光分子探针及其合成和使用方法，发明专利，专利号ZL201510785171.4，授权日期2017.04。

16.赵冰，阮耀宇，阚伟，王丽艳，邓启刚。一种多取代咪唑杯芳烃衍生物及制备方法，发明专利，专利号ZL 201310015856.1，授权日期2015.09。

17.赵冰，阚伟，刘卓，王丽艳，宋波，邓启刚。一锅法合成噻唑并[3,2-a]嘧啶类衍生物的方法，发明专利，专利号ZL201310016623.3，授权日期2015.04。

18.赵冰，阚伟，刘卓，王丽艳，邓启刚。一种多取代噻二唑并[3,2-a]嘧啶-6-羧酸酯衍生物的微波合成方法，发明专利，专利号ZL201310052797.5，授权日期2015.02。

19.邓启刚，陈朝晖，赵冰。一种亚麻织物后整理工艺，发明专利，专利号ZL 2009 1 0071368，授权日期2012.08。

专著或教材

1.宋波，阚伟，赵冰.淀粉化学品，哈尔滨工程大学出版社，2009.08。

2.赵冰.有机化学反应与有机材料研究，中国水利水电出版社，2014.10。